In a breakthrough that touches the icy edge of physics, a Spanish professor has solved a century-old puzzle that stumped some of the greatest minds in scienceâincluding Albert Einstein.
In a recent paper published in The European Physical Journal Plus, JosĂ© MartĂn-Olalla of the University of Seville has established, for the first time, a direct theoretical link between Nernstâs theoremâan early 20th-century observation about entropy at low temperaturesâand the second law of thermodynamics, which governs the irreversible increase of entropy in the universe.
This might sound like an abstract reshuffling of dusty physics principles, but in reality, it marks a profound shift in our understanding of the deepest workings of nature. It revisits an argument first posed by Walther Nernst in 1905 and later dismissed by Einstein, and in doing so, it may reshape how thermodynamics is taught, interpreted, and understood for generations to come.
At the Edge of Zero: The Birth of a Theorem
In the early 1900s, scientists were just beginning to understand how matter behaves at temperatures nearing absolute zeroâa chilling -273°C, where molecular motion essentially stops. Walther Nernst, working at the crossroads of chemistry and physics, observed something peculiar and consistent: as the temperature of a system approached absolute zero, the entropy exchangesâthe measure of disorder or randomness in a systemâtended to zero.
He formulated this into what we now call Nernstâs theorem, or sometimes the third law of thermodynamics. Nernst argued that if absolute zero were ever attainable, it would allow for the theoretical creation of a perfect engineâone that converts all heat into useful work with no waste. Such an engine would break the sacred second law of thermodynamics, which insists that disorder must always increase.
So, Nernst concluded: absolute zero must be fundamentally unreachable.
But then came Einstein.
Einstein’s Rebuttal: Separating the Laws
Einstein, never one to take even the sharpest logic at face value, raised an objection. He agreed that such a perfect engine was theoretically problematicâbut insisted that it was impossible to construct such a device in practice. And because it couldn’t exist, he argued, it couldnât serve as a foundation for proving anything about the second law. The impossibility of reaching absolute zero, then, must be a separate principle altogetherânot an extension of entropyâs law, but an independent third principle.
That viewpoint stuck. For over a century, physicists have treated Nernstâs observation as an axiom of its ownâfloating near the edge of our physical understanding but isolated from the foundational laws that govern heat, work, and entropy.
Now, MartĂn-Olalla says that division was a mistake.
A Virtual Engine and the Return to Unity
In his bold reanalysis, MartĂn-Olalla doesnât rely on new experimental data or exotic technology. He revisits the very assumptions that framed the original argumentâand finds that something crucial was missing all along.
Nernst imagined a machine that could violate the second law. Einstein responded that the machine was impossible. But MartĂn-Olalla adds a vital nuance: the machine was never meant to be real. It was, and should have always been understood as, a virtual constructâa thought experiment engine that neither consumes heat nor produces work.
In this light, the second law of thermodynamics doesnât demand the machine be real. It only requires its theoretical presence to reason about the limits of entropy. And if the machine is understood as a mathematical fiction, not a physical object, then the logic Nernst used holds trueânot in opposition to the second law, but as a direct consequence of it.
âWhen you approach the second law in its formal version,â MartĂn-Olalla explains, âyou find that the engine Nernst imagined is not only compatible with the lawâitâs required. But it must remain virtual. That changes everything.â
Rethinking Absolute Zero
This isnât just a semantic twistâit fundamentally alters how physicists might conceptualize temperature itself.
As MartĂn-Olalla notes, we often think of hot and cold as sensations. Even when we study temperature scientifically, we rely on empirical markers: the pressure of a gas, the expansion of a metal rod. But none of those tools approach the theoretical clarity offered by entropy and the second law.
At absolute zero, entropy becomes uniqueâthere is only one microstate, one configuration of matter, and no uncertainty remains. That uniqueness, MartĂn-Olalla argues, is what the second law demands. And the cancellation of specific heat, long treated as an independent quirk noted by Nernst in 1912, is merely an appendixâa corollary to the larger story.
Correcting Einstein?
In scientific circles, challenging Einstein is something done only with care, clarity, and exceptional evidence. MartĂn-Olalla does all threeânot by tearing down Einsteinâs work, but by reframing the debate.
Einstein correctly recognized that Nernstâs engine could not exist. But what MartĂn-Olalla shows is that the formal structure of thermodynamics never needed it to exist physically. It only needed the idea of it. Once that distinction is made, Nernstâs original conclusionâthat absolute zero is unreachable, and that entropy exchanges vanish as temperature nears itâemerges naturally from the second law.
This reintegration eliminates the need to treat the third law as something entirely separate. It becomes a logical extension, rather than a separate assumption.
Changing the ClassroomâAnd the Canon
As with all great theoretical breakthroughs, acceptance will take time. MartĂn-Olalla is candid about this.
âThe students in the thermodynamics course I teach were the first to learn about this demonstration,â he said. âI hope that with this publication the demonstration will become better known, but I know that the academic world has a great deal of inertia.â
But every revolution begins with a few thoughtful readers. And in a world where scientific attention is often dominated by flashy particles and astronomical headlines, thereâs something quietly profound about solving a puzzle that has lingered since the birth of modern physics.
Itâs a reminder that science moves not only by leaps in technology, but also by shifts in understandingâthat sometimes, to move forward, we must return to the foundations and look again, more carefully, at what we thought we knew.
With a virtual engine and a little imagination, MartĂn-Olalla may have just changed the way we think about cold, entropy, and the laws of the universe. And he did it not by breaking the rulesâbut by showing how they were always meant to work.
Reference: Jos-MarĂa MartĂn-Olalla, Proof of the Nernst theorem, The European Physical Journal Plus (2025). DOI: 10.1140/epjp/s13360-025-06503-w
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